• 专利附录
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    • 专利摘要:
    Agent comprising a porous porous breathable film 14, a breathable filler film comprising from about 50% to about 70% by weight of a filler and an amorphous polymer such as an elastomeric ethylene polymer having a density of preferably less than 0.89 g / cm 3. A breathable barrier laminate 10 is disclosed having a third fibrous layer comprising a two film layer 16 and a breathable outer layer 22, such as a nonwoven web of spunbond fibers. The multilayers can be laminated by heat, and the laminate has a peel strength greater than 200 g and a WVTR greater than 300 g / m 2 / day.
    公开号:KR20010023957A
    申请号:KR1020007002666
    申请日:1998-09-15
    公开日:2001-03-26
    发明作者:윌리엄 벨라 해프너；앤 루이스 맥코어맥
    申请人:로날드 디. 맥크레이；킴벌리-클라크 월드와이드, 인크.；
    IPC主号:
    专利说明:

    Breathable Filled Film Laminate
    Currently, there are a variety of fabrics that act as barriers for particulate matter, water and other liquids but can permeate water vapor and air. Such fabrics are commonly referred to as "breathable barriers". Breathable barrier fabrics have been used in outdoor fabrics, tarpaulins, garments, personal care products, infection suppression products, as well as many other articles. Moreover, breathable barrier fabrics are often preferred over non-breathable barrier materials because the breathable barrier fabric releases moisture that has permeated deep into the fabric as water vapor. Thus, garments using breathable barrier fabrics are generally more comfortable when worn, as they reduce and eliminate (or less) the skin discomfort caused by excess moisture seeping out by releasing water vapor through the fabric.
    Although various breathable barrier fabrics are known in the art, one particularly useful breathable barrier includes elongated microporous filler films. Such films are typically compacted or stretched after being filled with particles or other materials to form microporous networks, which create a tortuous path through the film. The film pore network acts as a barrier for liquid and particulate materials, while allowing gas and water vapor to permeate the film. The amount and elongation of filler in the film is adjusted to produce a microporous network of desired size and / or frequency to impart the desired level of breathability to the fabric. Examples of stretched fill films are described in McCormack's co-assigned WO Patent Application No. 95/16562, which contains a linear polyolefin polymer as the main component, a binder and 30 to 80% by weight of carbonic acid. An elongated filling film comprising calcium is disclosed. The filled polyolefin film can be stretched to impart breathability to the film. The stretched film is then laminated to the nonwoven web to form a laminate that has advantages in the integrity and strength of the nonwoven web and in blocking the stretched film.
    Thin films, which can be produced by stretching or orienting the filling film, often crack or tear easily in the orientation direction. Thus, as mentioned above, the stretched fill film is often laminated to the support layer to provide additional strength and integrity to the film. The peel strength of the laminate is preferably strong enough to withstand delaminations that may be caused by further processing, transport and / or storage of the laminate. Often, laminates are exposed to high temperature and wet conditions. Moreover, the laminate preferably also withstands lamination which may result from the mechanical stresses applied to the laminate in use. As an example, wearing a garment or diaper incorporating a barrier laminate stresses the laminate as a result of wear, pull, and other manipulation of the article. In addition to the naturally occurring deformations of clothing, many of today's articles use a variety of fasteners, such as tape or hook and loop systems, which create additional deformations in the laminate by pulling the outer layers. Examples of fastening systems are co-assigned U.S. Patent No. 5,605,735 to Zehner et al., Co-assigned U.S. Patent No. 5,019,073 to Roessler et al., Co-assigned U.S. Patent No. 5,624,429 US patent application Ser. No. 08 / 534,227, filed Sep. 26, 1995, issued jointly to Rossler, et al. As a result of the pull caused by the fasteners, many nonwoven / film laminates begin to peel or delaminate and separate the film from the support fabric. In this regard, the film breaks or tears considerably more easily once it is separated from the support fabric. Thus, stratification ultimately impairs barrier properties, ie leakage occurs in the article. In addition, even if lamination occurs in areas around the edge of the product where barrier properties are less important, for example, lamination is undesirable in terms of aesthetics and degrades the appearance quality of the product. Therefore, the breathable barrier laminate with good peeling strength is more preferable.
    However, laminating the breathable thin film on at least one support layer in a manner that achieves the desired peel strength is particularly difficult without reducing the barrier property and / or the breathability of the film. Generally speaking, when thermally bonding two layers of thermoplastic material together, better lamination or peel strength can be achieved by increasing the adhesion temperature and / or increasing the overall adhesion area. Thermal bonding of thin films and support layers at temperatures necessary to increase the peel strength often results in "burn through" or nip holes in the film, which degrades barrier properties. This is, of course, very undesirable for fabrics which want to make the film act as a barrier to substances such as urine and other body secretions, and moreover if the film is used as a barrier against substances that pose a risk, for example blood. It is more problematic. In addition, point adhesion often impairs the breathability of the fabric in the adhesive area, so increasing the overall adhesion area may undesirably lower the breathability of the laminate. Excessive thermal adhesion can also undesirably also reduce the flexibility and feel of the resulting laminate. Moreover, the lamination of the breathable thin film and the support fabric with an adhesive can often stratify as a result of the physical and mechanical stresses that the breathable barrier laminate also suffers from. In addition, certain adhesives can reduce the breathability of the laminate and / or undesirably stiffen the laminate.
    Accordingly, there is a need for a breathable barrier laminate having good breathability and barrier properties and excellent peel strength. Moreover, there is also a need for breathable barrier laminates that are good to the touch, durable and that can utilize various films and laminated structures. There is also a need for breathable barrier laminates that can be manufactured in a robust manner that is functional under a wide range of processing conditions and variables.
    <Summary of invention>
    With the breathable barrier laminate of the invention comprising a breathable base film, a breathable amorphous polymer interlayer and a breathable fibrous outer layer adhered thereto, the above needs are met and the problems experienced by those skilled in the art are overcome. Preferred is a base film comprising a breathable microporous barrier film having a WVTR (Water Vapor Transmission Rate) of 100 g / m 2 / day. Preference is given to an interlayer having a first side and a second side, comprising a breathable filler film comprising a low density ethylene elastomer having a density of less than about 0.89 g / cm 3 and at least about 50 wt% filler. The first side of the intermediate layer is substantially continuously bonded to the base film, and the second side is juxtaposed to the fibrous layer. The fibrous outer layer is preferably laminated on the second side of the intermediate layer, wherein the laminate has a peel strength of at least 200 g and the total laminate has a WVTR of 100 g / m 2 / day.
    In another aspect, the low density ethylene elastomer component preferably comprises a copolymer of ethylene with an alpha-olefin polymer such as, for example, substantially linear polyethylene. Also preferred are low density ethylene elastomers having a density of about 0.86 g / cm 3 to about 0.89 g / cm 3. The interlayer also comprises a second polyolefin polymer, such as a second ethylene copolymer. Preference is given to low density ethylene elastomers comprising at least about 50% by weight of the intermediate filler film in the polymer proportions.
    In another aspect, the breathable base film may comprise a polyolefin polymer and a filler, preferably a linear low density polyethylene filler film elongated to impart breathability to the film. The total basis weight of the base film and the intermediate film is preferably less than about 50 g / m 2, and the intermediate layer is preferably less than about 30% of the combined thickness of the base film and the intermediate layer. The base film preferably comprises about 35% to about 65% by weight filler, such as calcium carbonate particles. In another aspect, the breathable filler interlayer preferably has a weight percent filler content of substantially the same and / or higher content of the base film.
    In another aspect, the breathable fibrous layer may comprise a nonwoven fabric. Preferably the fibrous layer comprises a nonwoven web having a basis weight of about 8 g / m 2 to about 70 g / m 2, such as a propylene polymer fiber spunbond web. The breathable barrier laminate of the present invention preferably has a peel strength of greater than 200 g, more preferably greater than 300 g and / or greater than 500 g. In addition, the WVTR of the breathable barrier laminate preferably exceeds 300 g / m 2 / day, 800 g / m 2 / day, even 1500 g / m 2 / day. The outer layer can be laminated to the adhesive layer by thermally bonding the respective layers to each other, ie by melting one or more polymers. Suitable methods for laminating the layers include, but are not limited to, thermal bonding, ultrasonic bonding, infrared bonding, and the like. The base film, outer layer, and / or laminate may be elastic or inelastic.
    <Definition>
    As used herein, the term "nonwoven or nonwoven web" refers to a web having a structure of individual fibers or yarns that may be sandwiched or not identified in the same way as in knitted fabrics. Nonwoven or nonwoven webs have been formed in several ways, such as, for example, meltblown methods, spunbond methods, entanglement, air-laid and bonded carded web methods.
    As used herein, the term "spunbond fibers" refers to small diameter fibers of molecularly oriented polymeric material. Spunbond fibers can be formed by extruding molten thermoplastic material as filaments from a plurality of fine generally circular capillaries having a rapidly decreasing diameter following the diameter of the filament from which the spinneret is extruded (e.g., apel ( US Pat. No. 4,340,563 to Appel et al., US Pat. No. 3,692,618 to Dorschner et al., US Pat. No. 3,802,817 to Matsuki et al., Kinney et al. U.S. Patent Nos. 3,338,992 and 3,341,394, US Pat. No. 3,502,763 to Hartman et al., US Pat. No. 3,542,615 to Dobo et al. And US Patent No. to Pike et al. 5,382,400). Spunbond fibers are generally non-tacky and generally continuous when deposited onto an integrated surface. Spunbond fibers are often at least 10 microns in diameter. However, fine fiber spunbond webs (with an average fiber diameter of less than about 10 microns) are described in US Patent Application No. 08 / 756,426 and Pike et al., Filed Nov. 26, 1996, jointly assigned by Marmon et al. It may be obtained through a variety of methods, including but not limited to the method described in commonly assigned US patent application Ser. No. 08 / 565,261, filed November 30, 1995.
    As used herein, the term “meltblown fibers” generally extrudes a molten thermoplastic material through a plurality of fine, generally circular die capillaries as molten sand or molten filaments to provide a high speed, generally hot gas (ie, air). ) Fiber formed by thinning the filaments of the molten thermoplastic material by reducing the diameter thereof to a stream. Thus, the meltblown fibers are carried by the high velocity gas stream and are deposited on an integrated surface to form a web of randomly distributed meltblown fibers. Such a process is disclosed, for example, in US Pat. No. 3,849,241 to Butin et al. Meltblown fibers can be continuous or discontinuous, and generally have an average diameter of less than 10 microns and are generally tacky when deposited on an integrated surface.
    As used herein, a "multilayer nonwoven laminate" refers to, for example, two or more layers of nonwoven layers, such as spunbonded and some meltblown, such as spunbond / meltblown / spunbond (SMS) laminates. Means laminate. Examples of multilayer nonwoven laminates are disclosed in US Pat. No. 4,041,203 to Brock et al., US Pat. No. 5,178,931 to Perkins et al. And US Pat. No. 5,188,885 to Timmons et al. have. Such laminates are successively deposited onto a running forming belt, first by spunbond fabric layer, then by meltblown fabric layer, and finally by another spunbond layer, and then by adhering the laminate, for example, by thermal point bonding as described above. It can manufacture by making it. Alternatively, the fabric layers can be prepared by collecting them separately from the rolls and combining them in separate bonding steps.
    As used herein, the term "longitudinal" or MD means the lengthwise direction of the fabric from which the fabric is made. The term "lateral" or CD means the width of the fabric, i.e. generally the direction perpendicular to the MD.
    The term "polymer" as used herein generally includes, but is not limited to, homopolymers, copolymers such as blocks, grafts, random and alternating copolymers, terpolymers, and the like, and blends and variants thereof. It is In addition, the term "polymer" includes all possible geometries of the material unless otherwise specified. These arrangements include, but are not limited to, isotactic, syndiotactic, and random symmetry.
    As used herein, the term "soft polyolefin" refers to a polymeric microporous oriented film having a flexible polyolefin and a method for preparing the same, the entire contents of which are incorporated herein by reference. Methods of making the Same "as described in US Patent Application No. 08 / 775,087 to Hetzle and Jacobs, filed Dec. 30, 1996. Polyolefin materials containing a propylene based polymer, which are adjusted to achieve the desired crystallinity, are referred to.
    The term "amorphous polymer" as used herein, when used to describe an adhesive layer as a multilayer film component or as a separately used layer, has a specific density of about 0.85 to about 0.89 and a low crystallinity, for example, of less than about 30%. It means a thermoplastic polymer such as polyolefin.
    As used herein, “ultrasound bonding” is used to pass a fabric between a sonic horn and anvil roll, as illustrated, for example, in US Pat. No. 4,374,888 to Bornslaeger. Means a method to be carried out by.
    As used herein, “point bonding” means bonding one or more fabric layers at a plurality of discrete bond points. For example, thermal point bonding generally involves passing one or more layers to be bonded between heated rolls, such as a stamped pattern roll and a smooth calendar roll. The stamped rolls are patterned in some way so that the entire fabric is not glued across its entire surface, and the anvil rolls are generally flat. As a result, various patterns for imprinted rolls have been developed for functional as well as aesthetic reasons. One example of the pattern is Hansen with a 30% adhesive area of about 0.13 adhesion / m 2 (200 adhesion / inch 2 ) with dots, as taught in US Pat. No. 3,855,046 to Hansen and Pennings. Is a pennings or "H &P" pattern. The H & P pattern has a square point or pin adhesion area where each pin has a lateral dimension of 0.965 mm (0.38 inch), a pin spacing of 1.778 mm (0.070 inch), and an adhesion depth of 0.584 mm (0.023 inch). The resulting pattern has an adhesive area of about 29.5%. Another typical point adhesive pattern is an extended Hansen Pennings or "EHP" adhesive pattern, which has a lateral index of 0.94 mm (0.037 inch), a pin spacing of 2.464 mm (0.097 inch) and an adhesive depth of 0.991 mm (0.039 inch) Create a 15% adhesive area as square pin with. Another typical dot bonding pattern designed as "714" is a square pin with each pin having a side index of 0.584 mm (0.023 inches), a pin spacing of 1.575 mm (0.062 inches) and an adhesive depth of 0.838 mm (0.033 inches). Has an adhesive area. The resulting pattern has an adhesive area of about 15%. However, another common pattern is a C-Star pattern with an adhesive area of about 16.9%. The Sea-Star pattern has a "corduroy" design that is interrupted by cross-directional bars, or "oily" shapes. Other common patterns include diamond patterns with repetitive and slightly offset diamonds (about 16% adhesion area), and wire wave patterns (about 17% adhesion area) as suggested names, for example window screens. . Typically, the% adhesive area varies from less than about 50%, more preferably from about 10% to about 30% of the fabric laminate web area.
    The term "barrier" as used herein means a film, laminate or other fabric that is relatively liquid impermeable and has a hydrohead of at least 50 mbar of water. As used herein, the term hydrohead refers to a measure of the liquid barrier properties of the fabric. However, for barrier fabrics of various uses, including the barrier fabric of the present invention, it may be desirable for the hydrohead value to be greater than about 80 mbar, greater than 150 mbar, or even greater than 300 mbar of water.
    As used herein, the term "breathable" refers to a material that is permeable to water vapor with a minimum WVTR of about 100 g / m 2/24 hours. The WVTR of the fabric is water vapor transmission, and on one side it represents the degree of comfort of the fabric when worn. WVTR (water vapor permeability) is measured as indicated below, and the result is expressed in units of g / m 2 / day. However, it is often desirable to use a breathable barrier with a higher WVTR, and the WVTR of the breathable barrier of the present invention exceeds about 300 g / m 2 / day, exceeds 800 g / m 2 / day, or 1500 g / m 2 / Or more than 3000 g / m 2 / day.
    As used herein, the term "monocomponent fiber" refers to fibers formed from one or more extruders using only one polymer. This does not exclude fibers formed of one polymer to which a small amount of additive is added for color, antistatic property, lubricity, hydrophilicity, and the like. As used herein, the term "multicomponent fibers" refers to fibers formed of two or more polymers extruded from separate extruders but spun together to form one fiber. Multicomponent fibers are also sometimes referred to as composite or bicomponent fibers. The polymers of the multicomponent fibers are positioned substantially uniformly in separate zones across the cross section of the fiber and are arranged to extend continuously along the length of the fiber. Such an arrangement of fibers may be, for example, a sheath / core alignment, side by side alignment, pie alignment or “islands” that surround one polymer with another polymer. -in-the-sea "type alignment. Multicomponent fibers are taught in US Pat. No. 5,108,820 to Kaneko et al., US Pat. No. 4,795,668 to Krueger et al. And US Pat. No. 5,336,552 to Strack et al. have. Composite fibers are also taught in US Pat. No. 5,382,400 to Pike et al. And can be used to crimp the fibers using two (or more) polymers with different crystallization properties. Corrugated fibers can also be produced by the method of German patent DT 25 13 251 A1 by mechanical means. For bicomponent fibers, the polymer may be present at 75/25, 50/50, 25/70 or other desired ratios. Fibers are also described in US Pat. No. 5,277,976 to Hogle et al., US Pat. No. 5,466,410 to Hills, US Pat. No. 5,069,970 to Lagman et al. And US Pat. No. 5,057,368 (e.g., US Pat. Fiber of an unusual shape).
    The term "blend" as used herein refers to a mixture of two or more polymers, while the term "alloy" refers to a subclass of blend in which the fiber components are immiscible but blended.
    As used herein, the term "bielement fiber" or "multielement fiber" refers to a fiber formed of two or more polymers extruded as a blend from the same extruder. The term "blend" is as defined above. Bicomponent fibers do not contain various polymer components arranged to be relatively uniformly positioned in individual zones across the cross section of the fiber and are generally random at the beginning and end, instead of being generally discontinuous along the entire length of the fiber. To form fibrils or fibrils. Bicomponent and bicomponent fibers are also described in the polymer blends and composites by John A. Manson and Leslie H. Sperling, copyright 1976 by Plenum Press, a division of Plenum Publishing Corporation of New York, ISBN 0-306-30831-2, at pages 273-277.
    As used herein, the term "bonding window" refers to the mechanism used to bond the nonwovens together, for example the temperature range of a pair of heated adhesive rolls, and such bonding is successful.
    As used herein, the term "scrim" refers to a light weight fabric used as the backing material. Scrims are often used as base fabrics for coated or laminated articles.
    As used herein, the term "garment" refers to a wearable type of garment derived from non-medical use. Garments include industrial workwear and cover rolls, underwear, pants, shirts, jackets, gloves, socks and the like.
    As used herein, the term "infection suppression article" refers to items derived from medical use, such as surgical gowns and drapes, face masks, head covers such as head caps, surgical caps and hoods, shoe covers, boot covers, boots Covers and slippers, wound dressings, bandages, sterile wraps, wipers, garments such as lab coats, cover rolls, aprons and jackets, patient beds, stretchers and baby carriage sheets and the like.
    As used herein, "personal hygiene article" means diapers, training pants, absorbent undergarments, adult incontinence supplies and feminine hygiene articles.
    The term "protective cover" as used herein refers to outdoor devices (grass mowers, cultivators, etc.) such as vehicles, trucks, boats, aircraft, motorcycles, motorcycles, golf vehicles, etc. And covers often used in lawn equipment, as well as floor coverings, tablecloths and outing covers.
    The present invention relates to a breathable filling film. More specifically, the present invention relates to a breathable filling film having high peel strength and a laminate thereof.
    1 is a cross-sectional view of a breathable barrier laminate of the present invention.
    2 is a cross-sectional view of the breathable barrier laminate of the present invention.
    3 is a schematic representation of a process line for making the breathable barrier laminate of the present invention.
    Referring to FIG. 1, the present invention relates to a breathable barrier laminate 10 comprising a multilayer film 12 and a fibrous outer layer 22. The multilayer film 12 may include a first breathable substrate layer 14 and an adjacent breathable intermediate layer 16. The breathable intermediate layer 16 has a first side 18 and a second side 20. The fibrous outer layer 22 is attached to the second face 20 of the breathable intermediate layer 16, and the breathable base layer 14 is attached to the first face 18 of the breathable intermediate layer 16.
    The breathable base layer includes a breathable film. For example, the breathable substrate layer has a WVTR greater than 100 g / m 2 / day, preferably greater than 300 g / m 2 / day, more than 800 g / m 2 / day, or 1500 g / m 2 / day. Microporous films that exceed or even greater than 3000 g / m 2 / day. The breathable substrate layer 12 may be formed by one of several methods known in the art. Preferably, the first breathable barrier layer comprises an elongated filler film comprising a thermoplastic polymer and a filler. These (and other) components are mixed together and heated, and then extruded into a single or multilayer film. Filling films can be produced by one of several film forming methods known in the art, for example using cast or blown film devices. Preferably, the breathable base film and the breathable interlayer can be produced simultaneously, for example via coextrusion. As an example, a method of forming a multilayer film is disclosed in US Pat. Nos. 4,522,203, 4,494,629, 4,734,324 and WO 96/19346, the entire contents of which are incorporated herein by reference.
    In a preferred embodiment, the substrate layer is a breathable barrier made of a thermoplastic polymer and comprising a thin film that is stretched in at least one direction to reduce film thickness or thickness. Thermoplastic polymers used in the manufacture of the films of the present invention include, but are not limited to, polyolefins including homopolymers, copolymers, terpolymers, and blends thereof. In addition, soft polyolefin films or "polyolefin based" films are also considered suitable for use in the present invention. For the purposes of the present invention, when the polymer portion of the film contains at least 50% by weight of polyolefin, excluding all filler materials, the polymer is considered to be "polyolefin based". Additional film forming polymers that may be suitable for use alone or in combination with other polymers in the present invention include ethylene vinyl acetate (EVA), ethylene ethyl acrylate (EEA), ethylene acrylic acid (EAA), ethylene methyl acrylate (EMA) , Ethylene standard butyl acrylate (EnBA), polyester, polyethylene terephthalate (PET), nylon, ethylene vinyl alcohol (EVOH), polystyrene (PS), polyurethane (PU), polybutylene (PB) and polybutylene Terephthalate (PBT). However, polyolefin polymers such as, for example, polymers of ethylene and propylene, and copolymers thereof, terpolymers and blends (including but not limited to linear low density polyethylene (LLDPE) and ethylene-propylene copolymer blends) Is preferred.
    Breathable stretched fill film may further comprise, in addition to the thermoplastic polymer, fillers that impart breathability to the film upon stretching. As used herein, a "filler" may be added to a film polymer extrusion blend that does not chemically interfere with or adversely affect the extruded film and may also be dispersed uniformly throughout the film and / or other forms. Contains the substance of. Generally, the filler is in the form of particles having an average particle size of about 0.1 to about 10 microns, preferably about 0.1 to about 4 microns. The term "particle size" as used herein refers to the maximum diameter or length of a filler. Both organic and inorganic fillers are contemplated for use in the present invention as long as they do not interfere with the film forming process and / or subsequent lamination processes. Examples of fillers include calcium carbonate (CaCO 3 ), various clays, silica (SiO 2 ), alumina, barium sulfate, talc, magnesium sulfate, titanium dioxide, zeolite, aluminum sulfate, cellulose powder, diatomaceous earth, gypsum, magnesium sulfate, Magnesium carbonate, barium carbonate, kaolin, mica, carbon, magnesium oxide, aluminum hydroxide, pulp powder, wood flour, cellulose derivatives, polymer particles, chitin and chitin derivatives. The filler particles may optionally be coated with fatty acids such as stearic acid or behenic acid and / or other materials to facilitate free flow of the particles (bulk) and dispersion into the polymer. With reference to the base film, the filler film generally contains at least about 35% by weight, more preferably from about 45% to about 65% by weight filler, based on the total amount of the base film layer.
    In addition, the base film may optionally include one or more stabilizers. Preferably, the fill film comprises an antioxidant such as, for example, a hindered phenol stabilizer. Commercially available antioxidants include IRGANOX® E17 (α-tocopherol) and IRGANOX® 1076 (octodecyl 3,5-di-tert) available from Ciba Specialty Chemicals, Terrytown, NY. -Butyl-4-hydroxyhydrocinnamate), but is not limited thereto. It is preferred to add about 100 to 1000 ppm of stabilizer to the base polymer (s) before extrusion (ppm refers to the total amount of the fill film). In addition, other stabilizers or additives that may be used in the film forming process, stretching and any subsequent lamination steps may also be used in the present invention. For example, additional additives (such as melt stabilizers, process stabilizers, heat stabilizers, light stabilizers, thermal aging stabilizers, and other additives known to those skilled in the art) may be added to provide the desired properties to the film. You can give it. Generally, phosphite stabilizers (e.g., IRGAFOS® 168 available from Ciba Specialty Chemicals, Terrytown, NY, and Dover Chemical Corp., Dover, Ohio) DOVERPHOS ™ is a good melt stabilizer, while hindered amine stabilizers (e.g., CHIMASSORB ™ 944 and 119 available from Ciba Specialty Chemicals, Terrytown, NY) are good thermal and light stable It is a topic.
    The breathable interlayer 16 includes two or more components, including amorphous polymer components and fillers. Preferred are polymer components comprising low density ethylene elastomers comprising ethylene copolymers having a density of less than about 0.89 g / cc, preferably from about 0.86 g / cc to about 0.88 g / cc, more preferably about 0.87 g / cc. Do. Preferably, the ethylene elastomer comprises polyethylene that is substantially linear. Preference is given to ethylene elastomers comprising at least about 50%, more preferably from about 70% to 100% by weight of the polymer portion of the interlayer. Preferably, the ethylene elastomer comprises a polymer wherein the polymer composition produced by polymerizing the ethylene monomer with an alpha-olefin has a narrow molecular weight distribution (Mw / Mn), homogeneous branching and controlled long chain branching of about 2. Suitable alpha-olefins include but are not limited to 1-octene, 1-butene, 1-hexene and 4-methyl-pentene. Examples of polymers include US Pat. No. 5,472,775 to Obijeski et al., US Pat. No. 5,451,450 to Edderly et al., US Pat. No. 5,204,429 to Kaminsky et al. As described in US Pat. No. 5,539,124 to Etherton et al. And US Pat. No. 5,554,775 to Krishnamurti et al., The entire contents of which are incorporated herein by reference. Included are those prepared using metallocene "catalysts," constrained form "catalysts or" single point "catalysts.
    Metallocene processes generally use metallocene catalysts activated by cocatalysts, ie ionized. Examples of metallocene catalysts include bis (n-butylcyclopentadienyl) titanium dichloride, bis (n-butylcyclopentadienyl) zirconium dichloride, bis (cyclopentadienyl) scandium chloride, bis (indenyl) Zirconium dichloride, bis (methylcyclopentadienyl) titanium dichloride, bis (methylcyclopentadienyl) zirconium dichloride, cobaltocene, cyclopentadienyltitanium trichloride, ferrocene, hafnocene dichloride, isopropyl ( Cyclopentadienyl-1-fluorenyl) zirconium dichloride, molybdocene dichloride, nickellocene, naobosene dichloride, luthenocene, titanocene dichloride, zirconocene chloride hydrate, zirconocene di Chlorides and the like. A more detailed record of such compounds is contained in US Pat. No. 5,374,696 to Rosen et al. And assigned to Dow Chemical. Such compounds are also discussed in US Pat. No. 5,064,802 to Stevens et al. And also assigned to Dow. However, many other metallocenes, single point catalysts, and / or similar catalyst systems are also known in the art (eg, The Encyclopedia of Chemical Technology, Kirk-Othemer, Fourth Edition, vol. 17, Olefinic Polymers, pp. 765-767 (John Wiley & Sons 1996).
    US Pat. No. 5,204,429 to Kaminsky et al. In connection with metallocene based elastomeric polymers is intended to prepare elastomeric copolymers from cycloolefins and linear olefins using catalysts that are stereohard chiral metallocene transition metal compounds and aluminoxanes. It describes how you can do it. The polymerization is carried out in an inert solvent such as aliphatic or cycloaliphatic hydrocarbons (such as toluene). US Pat. Nos. 5,278,272 and 5,272,236, all of which are hereby assigned to Lai et al. And assigned to Dow Chemical, "Elastic Substantially Linear Olefin Polymers." (Which is incorporated by reference), describes polymers with specific elasticity. Suitable low density ethylene elastomers are Dow Chemicals, Midland, Michigan, under the trade names AFFINITY EG8200 (5 MI), XU 58200.02 (30 MI), XU 58300.00 (10 MI), and the trade name EXACT TM 4049 (4.5 MI, 0.873 g / cc); 4011 (2.2 MI, 0.888 g / cc); 4041 (3 MI, 0.878 g / cc; 4006 (10 MI, 0.88 g / cc) available from Exxon Chemical Co., Houston, TX, USA.
    The polymer component of the interlayer can comprise up to about 50% by weight of one or more additional polymers, in addition to the amorphous polymer. Thus, the interlayer may also comprise further thermoplastic polymers, preferably blends and / or copolymers of polyolefins, more preferably ethylene and / or propylene. Examples of polymers include, but are not limited to, polyethylene (homopolymer), linear low density polyethylene, EVA, EMA, EnBA, soft polyolefins, and / or ethylene-propylene copolymers. In one embodiment, the low density ethylene elastomer is blended with a second polyethylene polymer having a density range of about 0.90 to about 0.95 g / cm 3. Additional commercially available polyolefin polymer components include, but are not limited to, Himont Catalloy Polymers KS350, KS357, and KS359. Himont Catalloy polymers are the products of olefinic multistage reactions in which amorphous ethylene propylene random copolymers are dispersed molecularly predominantly in semicrystalline high density propylene monomer / low density ethylene monomer continuous matrices, an example being given to Ogale. No. 5,300,365, which is incorporated herein by reference. In addition, the intermediate layer may preferably comprise a hot melt adhesive resin having a melt viscosity of at least 100,000 mPa.sec. Commercially available amorphous polyolefins used in hot melt adhesives suitable for use in the present invention include REXTAC ™ ethylene-propylene APAO E-4 and E-5 from Huntsman Corporation, Salt Lake City, UK, and butyl Len-propylene BM-4, BH-5 and 2503-3A, and VESTOPLAST ™ 792 from Huels AG, Marl, Germany, but are not limited to these. These amorphous polyolefins are generally synthesized on Ziegler-Natta supported catalysts and alkyl aluminum cocatalysts, and olefins such as propylene are polymerized with varying amounts of ethylene, 1-butene, 1-hexene or other materials to form primarily atactic hydrocarbon chains. Create Preferably, the hot melt adhesive resins likewise have a density of less than 0.89 g / cm 3 and a low glass transition temperature (less than about −10 ° C.) to improve flexibility and strength.
    In addition, the polymer component of the interlayer may further comprise additional additives or stabilizers as described above in connection with the breathable substrate layer. In addition, the polymer component may further comprise various extenders, waxes and other additives. In this regard, it is preferred that the melt viscosity of the additional polymer when processing the coextruded film is similarly greater than 100,000 mPa.sec. The melt viscosity of the components can be varied by adding extenders and waxes known to those skilled in the art.
    The filler component of the interlayer may comprise fillers of similar shape and content as discussed for the breathable stretched filler film discussed above in connection with the base film. If the breathable base layer comprises a filler film, it is preferred that the intermediate layer comprises at least about the same weight% of filler as the breathable base layer, and more preferably contains a greater weight percentage of filler than the breathable base layer. Preference is given to interlayers comprising at least about 45% by weight filler, more preferably from about 50% to about 65% filler.
    The preferred basis weight of the multilayer film 12 before stretching is less than about 100 g / m 2, more preferably less than about 60 g / m 2. The preferred basis weight upon stretching of the multilayer film is less than 60 g / m 2, more preferably about 15 to 35 g / m 2. Typically such lower basis weight films are from about 15 microns to about 30 microns thick. The base film preferably comprises about 50% to about 98% of the thickness of the multilayer film, and the intermediate fill film comprises about 2% to about 50%, more preferably about 5% to about 20% of the total thickness of the multilayer film. Achieve.
    The fibrous layer may comprise any breathable material that can be laminated and preferably supported in a multilayer film. The fibrous layer can include, for example, nonwoven webs, multilayer nonwoven laminates, scrims, wovens, and / or other similar materials. Preference is given to supporting fabrics comprising at least one layer of spunbond and / or meltblown fibrous webs. The composition of the thermoplastic polymer can be selected as needed to obtain a material having the desired properties: touch, beauty, tensile strength, price, wear resistance, hook engagement, and the like. In addition, the fibrous layer can be further processed, for example through embossing, entanglement, mechanical softening, printing, or in another way to obtain the desired beauty, feel or other properties. In this regard, it is possible to emboss a variety of eye-catching patterns in the nonwoven web, which is particularly desirable for various articles such as, for example, outer covers of baby diapers. In one embodiment, the outer layer comprises from about 10 g / m 2 to about 70 g / m 2, more preferably 10 g / m 2 to about 30 webs of polypropylene spunbond fibers printed and / or embossed in a uniform pattern. g / m 2 may be included.
    In another aspect of the invention, referring to FIG. 2, the breathable barrier laminate 50 may include a multilayer film 52 and outer layers 58a and 58b laminated to both sides of the multilayer film 52. have. The outer layer may comprise a material similar to that discussed above for the fibrous outer layer. When laminated to both sides of the multilayer film 52, the multilayer film 52 includes at least one first breathable substrate film 54, and breathable intermediate layers 56a and 56b on both sides of the substrate layer 54. It may often be desirable. Preferably, the intermediate layers 56a and 56b have a first side adhered to the base film 54 and a second side adhered to the respective outer layers 58a and 58b. The composition of the base film 54 corresponds to the breathable base layer 14 discussed above, and the composition of the intermediate layers 56a and 56b may correspond to the intermediate layer 16 discussed above. However, when the multilayer film comprises two intermediate layers, the thickness of the two films combined preferably constitutes about 50% or less, preferably about 5 to about 20%, of the total thickness of the multilayer film.
    3 is a schematic representation of a process line for making the breathable barrier laminate of the present invention. Referring to FIG. 3, the multilayer film 11 is formed from a film coextruder 100 such as a cast or blown unit as described above. Typically, coextruder 100 includes two or more polymer extruders 102. The unextended multilayer film 11 is extruded into a pair of nip or chill rollers 104, one of which can be patterned to provide an embossed pattern on the newly formed multilayer film 11. Using a two-layer film structure as shown in FIG. 1, the basis weight of the unstretched multilayer film 11 can be made less than about 100 g / m 2, more preferably less than about 60 g / m 2.
    The unstretched film 11 formed from the film coextruder 100 is a longitudinal aligner that may be a device commercially available from a vendor such as Marshall and Williams Company of Providence, Rhode Island. Is sent to the same film stretching unit 106. There are a number of preheating and stretching rollers in this unit 106 that make the non-stretched multilayer film 11 elongate in the longitudinal direction of the film (the direction in which the film 11 proceeds throughout the process) and thin. The film can be stretched in a single or multiple stretch operations. In addition, the film may be stretched in a plurality of directions (for example, in a biaxial direction). In FIG. 3, the heating rollers 108a and 108b can act as preheat rolls. Slow roll 110 is also heated to operate at a lower circumferential speed than fast roll 112. Adjacent rollers serve to stretch the multilayer film 11 at different speeds. After stretching, the film may be pulled slightly (or pulled) and further heated or annealed with one or more heated rollers, such as heated annealing roll 114. It may often be desirable to heat the multilayer film using rolls heated above the melting point of the amorphous polymer component in the interlayer. Thus, when using rolls heated above the melting point, the heated rollers must be in contact with the opposite side (eg breathable base film). After the film exits the stretching unit 106, the stretched multilayer film 12 preferably has a basis weight of less than about 60 g / m 2, more preferably about 15 to about 35 g / m 2.
    The multilayer film 12 is attached to one or more outer layers, such as the fibrous layer 22, to form the multilayer film / nonwoven laminate 10. Referring again to FIG. 3, a conventional fibrous nonwoven web former 110, such as a pair of spunbond groups, can be used to form the fibrous outer layer 22. The long, substantially continuous spunbond fibers 112 are deposited onto the forming wire 114 as an unbonded web 116 and then passed through a pair of crimp and / or adhesive rolls 118 for further processing. Add enough to impart integrity to the web during the process. Once the multilayer film 11 is sufficiently thin and the fibrous layer 22 is formed, the two layers are taken together and point bonded to each other using an adhesive such as a pair of heated adhesive rolls 116a and 116b. The adhesive rolls 116a and 116b are preferably heated and at least one roll can be inscribed with a discontinuous adhesive pattern on the adhesive surface of the laminate 10 resulting from patterning. In general, the maximum adhesion point surface area of one side of laminate 126 should not exceed about 50% of the total surface area of said one side of the laminate, preferably about 5-30%. There are various discrete adhesive patterns that can be used in the present invention. An example is a C-Star pattern such as point adhesion described in US Pat. No. 4,041,203 to Brock et al. Once the laminate 10 exits the adhesive or lamination rolls 116a and 116b, it may be wound on the winding roll 120. Alternatively, laminate 10 may be connected to a process line for further processing and / or conversion.
    The process shown in FIG. 3 can also be used to produce a multilayer laminate 50 as shown in FIG. 2. The second fibrous layer is fed into a lamination roll in contact with one side of the multilayer film opposite the first fibrous layer to form the laminate 50. The first and / or second support layer may be provided by a preform roll or formed directly on the same line. In addition, keeping the heated roll in contact with the interlayer below the melting point of the amorphous polymer prevents the film from adhering to the stretching unit.
    The barrier laminates of the present invention can be used to make or to form protective covers, infection suppression articles, personal care products, and garments and other articles that are desirably barrier and breathable. As an example of this, the barrier laminate may be a back sheet or outer cover of a diaper or adult incontinence garment as described in U.S. Patent No. 5,415,644 to Enloe, or a U.S. Patent to Morrell et al. It may be used as a surgical gown as described in US Pat. No. 4,823,404.
    <Test>
    Hydrohead: A measure of the liquid barrier of the fabric is the hydrohead test. The hydrohead test measures the height of the water or the amount of water pressure (in millibars) that the fabric can support before passing the liquid through. Fabrics with higher hydrohead matching indicate greater barrier to liquid permeation than fabrics with lower hydrohead. Hydroheads may be performed according to Federal Test Standard 191A, Method 5514. Hydrohead data cited herein were obtained using tests similar to the Federal Standard Tests described above, with the exception of the modifications indicated below. Heathrow is a Marlo Enterprise Inc. in Concord, North Carolina, USA. Measurements were made using a hydraulic head tester available from Marlo Enterprises, Inc. The specimens were placed under standard water pressure and the water pressure was increased at a constant rate until the first signs of leakage appeared on the fabric surface in three separate zones (ignoring leakage at the edges adjacent to the crimp). Unsupported fabrics, such as thin films, can be supported to prevent premature failure of the specimen.
    Melt Index: Melt index (MI) is a measure of polymer viscosity. MFR is expressed as the weight of material exiting a capillary tube of known dimensions under a specific load or shear rate during the measurement time and measured in g / 10 min at a load of 190 ° C. and 2160 g according to ASTM test 1238-90b.
    WVTR: Water vapor transmission (WVTR) for the sample material was calculated according to ASTM Standard E96-80. Circular specimens of 7.62 cm (3 inches) in diameter were cut from each test material and the control material, a fragment of CELGARD® 2500 film from Hoechst Celanese Corporation, Somerville, NJ. It was. CELGARD® 2500 film is a microporous polypropylene film. Three samples were prepared for each material. The test dish was a No. 60-1 Vaporometer pan, which was distributed by the Twin-Albert Instrument Company, Philadelphia, PA. 100 milliliters of water was poured into each baitometer pan and each sample of test material and control material was placed over the open top of each pan. The relevant test material or control material was sealed along the edges of the pans, with the screwed edges in close contact, exposed to room temperature on a 6.5 centimeter diameter circle with an exposure area of approximately 33.17 cm 2. The pan was placed in an air oven at 32 ° C. (100 ° F.) to equilibrate for 1 hour. The temperature of the oven was kept constant by circulating outside air throughout the oven to prevent water vapor from accumulating inside. Suitable air ovens are, for example, Blue M. Blue Island, Illinois, USA. Blue M Power-O-Matic 60, distributed by Blue M. Electric Company. When equilibrated, the pan was removed from the oven, weighed and immediately reloaded into the oven. After 24 hours, the pan was removed from the oven and weighed again. The water vapor transmission rate, a preliminary test, was calculated by the following equation (I).
    WVTR test = (g weight loss over 24 hours) × 315.5 g / m 2/24 hours
    The relative humidity in the oven was not particularly adjusted.
    Under pre-measured set conditions of 32 ° C. (100 ° F.) and ambient relative humidity, the WVTR for the CELGARD 2500 control material was specified to be 5000 g / m 2/24 hours. Thus, a control specimen was used for each test, and preliminary test values were corrected for the set conditions using Equation II below.
    WVTR = (Test WVTR / Control WVTR) × (5000 g / m2 / 24 hours)
    Peel Test: In the Peel or Lamination Test, the laminate is measured for the amount of tension needed to tear off the layers of the laminate. Peel strength values are obtained using a specific width of fabric, clamp width and elongation at constant speed. For samples with a film side, the film side of the specimen is covered with a protective tape or some other suitable material to prevent the film from tearing during the test. The protective tape is applied only to one side of the laminate so as not to affect the peel strength of the sample. The test uses two clamps with two straws, each in contact with the sample, and generally supports the material on the same side, spaced 5.08 cm (2 inches) from the initial position, vertically. The sample size is 10.16 cm (4 inches) wide and of sufficient length needed for stratification. The size of the cotton cloth is at least 2.54 cm (1 inch) high and 10.16 cm (4 inch) wide, with a constant elongation rate of 300 mm / min. The samples are layered by hand in an amount sufficient to clamp the sample to a suitable position, and the clamps are spaced at a specific elongation rate to tear the laminate. The sample specimen is torn apart so that the two layers are separated by 180 degrees and the peel strength is reported as the average peak of the load (in g). The measurement of force begins when the laminate is torn 16 mm and continues until a total of 170 mm is laid. Sintech 2 tester, available from Sintech Corporation, Carrie Sheldon Doctor 1001, 27513, USA; Instron model, available from Instron Corporation, St. 2500, Canton, Washington, USA 02021, USA TM, Pillar, PA 19154, USA. The Twin-Albert Model INTELLECT II, available from Twin-Albert Instruments, Duton Road 10960, can be used for this test. Results are reported as the average of three specimens and can be performed in the transverse (CD) or longitudinal (MD) direction for the specimen.
    <Example 1>
    A 55 g / m 2 multilayer film was formed via coextrusion. The adhesive layer comprises 45% by weight of SUPERCOAT ™ CaCO 3 coated with stearic acid, Dow AFFINITY ™ EG 8200 low density elastomeric polyethylene (catalyzed by metallocene, 0.87 g / cm3, melt index 5.0 g) It was. Substrate layer: 50% SUPERCOAT ™ CaCO 3 coated with stearic acid, DOWLEX ™ NG 3310 linear low density polyethylene (0.918 g / cm3, melt index 3.5 g) 45%, Dow 4012 LDPE (0.916 g / cm3, molten Index 12 g) 5% and a B900 stabilizer available from Ciba-Geigy. The interlayer made up about 10% of the total film thickness.
    The coextruded multilayer film was stretched longitudinally in a single band stretch operation using an MDO unit. The multilayer film was stretched 384% of its original length. Prior to stretching, the film was preheated with a series of “preheat” rolls of 48.9 ° C. (120 ° F.), slow rolls of 56.6 (150 ° F.), fast rolls of 21.1 (70 ° F.). The stretched multilayer film was annealed on an additional roll of 82.2 ° C. (180 ° F.) without additional tension. The annealed film was then introduced into the nip of a heat point gluer with a nonwoven web of propylene polymer spunbond fibers. The nonwoven web included 20 g / m 2 (0.6 osy) of about 2.0 denier spunbond fibers comprising propylene copolymer (3.5% ethylene). The nonwoven web was itself hot spot bonded in an s-weave pattern before introducing the stretched film into the nip. The bonded nonwoven web and stretched film are laminated together under a nip pressure of 3.4 atm (50 psi) using a heated patterned roll at 93.3 ° C. (200 ° F.) and a smooth steel anvil roll at 87.8 ° C. (190 ° F.). I was. An infant-shaped pattern (giving the laminate an adhesive area of about 15%) was imprinted on the patterning roll.
    The resulting laminate had a basis weight of 42 g / m 2, a longitudinal peel strength of 307 g (breakdown lamination), an unsupported hydrohead of 88 millibars, and a WVTR of 1195 g / m 2 / day.
    <Example 2>
    55 g / m 2 of cast “AB” film was formed via coextrusion. The adhesive layer is 60% SUPERCOAT ™ CaCO 3 coated with stearic acid, Dow AFFINITY® EG 8200 low density elastomeric polyethylene, available from English China Clay Co. of Silakoga, Alabama, USA. (0.87 g / cm 3, 5 MI) 20% by weight, Wheels America Inc., Somerset, NJ. 20% VESTOPLAST ™ 792 (Amorphous Propene-Rich Polyalphaolefin, 0.865 g / cc, Melt Viscosity at 190 ° C according to DIN 53019 125,000 mPa.sec) available from Huel's America, Inc. . Substrate layer is 50% SUPERCOAT® CaCO 3 coated with stearic acid, 45% DOWLEX NG 3310 linear low density polyethylene (0.916 g / cm 3, 3.5 MI) and Dow 4012 LDPE (0.916 g / cm 3, 12 MI) 5% was included. The outer layer or adhesive layer made up about 10% of the film thickness of the base layer and the adhesive layer.
    The coextruded multilayer film was stretched longitudinally in a single band stretch operation using an MDO unit. The multilayer film was stretched 380% of its original length. Prior to stretching, the film was preheated with a series of “preheat” rolls of 48.9 ° C. (120 ° F.), slow rolls of 56.6 (150 ° F.), fast rolls of 21.1 (70 ° F.). The stretched multilayer film was annealed on an additional roll of 82.2 ° C. (180 ° F.) without additional tension. The annealed film was then introduced into the nip of the thermal point gluer with a nonwoven web of propylene polymer spunbond fibers. The nonwoven web included 20 g / m 2 (0.6 osy) of 2.0 denier spunbond fibers comprising propylene copolymer (3.5% ethylene). The nonwoven web was itself hot spot bonded in an s-weave pattern before introducing the stretched film into the nip. The bonded nonwoven web and stretched film are laminated together under a nip pressure of 3.4 atm (50 psi) using a heated patterned roll at 93.3 ° C. (200 ° F.) and a smooth steel anvil roll at 87.8 ° C. (190 ° F.). I was. The patterning roll was imprinted with an infant-shaped pattern (giving an adhesive area of about 15% to the laminate).
    The resulting laminate had a basis weight of 39 g / m 2, longitudinal peel strength of 1340 g (breakdown lamination), an unsupported hydrohead of 92 millibars, and a WVTR of 272 g / m 2 / day.
    Although several patents and other references are incorporated herein by reference, there is some discrepancy between the cited materials and the present specification set forth and the specification set forth herein is to be adjusted. In addition, while the present invention has been described in detail with respect to particular embodiments thereof, it will be apparent to those skilled in the art that various changes, modifications, and other changes may be made without departing from the spirit and scope of the invention. Accordingly, all such modifications, changes and other variations are intended to fall within the scope of the appended claims.
    权利要求:
    Claims (30)
    [1" claim-type="Currently amended] A breathable base film comprising a thermoplastic polymer and having a WVTR (water vapor transmission rate) of 100 g / m 2 / day or more;
    A breathable intermediate film comprising an amorphous polymer and at least about 50% by weight of a filler, said breathable intermediate film having a first side and a second side and wherein said first side is adhered to said base film; And
    Breathable fibrous layer adhered to the second side of the intermediate film
    A breathable barrier laminate comprising: a peel strength of at least 200 g, a WVTR of at least about 100 g / m 2 / day, and a hydrohead of at least 50 millibars.
    [2" claim-type="Currently amended] The breathable barrier laminate of claim 1 wherein the amorphous polymer of the intermediate film comprises a copolymer of ethylene and an alpha-olefin and has a density of less than 0.89 g / cm 3.
    [3" claim-type="Currently amended] The breathable barrier laminate of claim 2 wherein the ethylene polymer comprises a copolymer of ethylene with an alpha-olefin selected from the group of 1-octene, 1-hexene, 1-butene and 4-methyl-pentene.
    [4" claim-type="Currently amended] The breathable barrier laminate of claim 1 wherein the amorphous polymer of the intermediate film comprises polyethylene that is substantially linear.
    [5" claim-type="Currently amended] The breathable barrier of claim 2 wherein the base film comprises an elongated polyethylene filled film having a WVTR greater than 300 g / m 2 / day and a breathable barrier having a WVTR greater than 300 g / m 2 / day. Laminate.
    [6" claim-type="Currently amended] The breathable barrier laminate of claim 5 wherein the base film comprises a polyethylene polymer and has a density greater than about 0.90 g / m 2.
    [7" claim-type="Currently amended] The method of claim 1, wherein the amorphous polymer of the intermediate film comprises ethylene elastomer having a density of about 0.86 g / cm 3 to 0.89 g / cm 3, and wherein the intermediate film comprises 1 to about 50 wt% of the second polyolefin polymer. Breathable barrier laminate.
    [8" claim-type="Currently amended] The breathable barrier laminate of claim 7 wherein said second polyolefin polymer comprises polyethylene polymer of a density greater than 0.90 g / cm 3.
    [9" claim-type="Currently amended] The breathable barrier laminate of claim 1 wherein the total basis weight of the base film and the intermediate film is less than 60 g / m 2 and the intermediate layer comprises less than about 20% of the combined thickness of the base film and the intermediate film. .
    [10" claim-type="Currently amended] The breathable barrier laminate of claim 2 wherein said intermediate layer comprises from about 50 wt% to about 65 wt% filler and comprises less than 30% of the total thickness of the intermediate film and the base film.
    [11" claim-type="Currently amended] The breathable barrier laminate of claim 10 wherein the base film comprises a polyolefin polymer and from about 35 wt% to about 65 wt% filler.
    [12" claim-type="Currently amended] The breathable barrier laminate of claim 11 wherein said base film comprises a polyethylene polymer and a filler.
    [13" claim-type="Currently amended] 13. The breathable barrier laminate of claim 12 wherein the filler content of the intermediate film is higher weight percent than the base film.
    [14" claim-type="Currently amended] The breathable barrier laminate of claim 12 wherein the base film comprises an ethylene polymer of a density greater than 0.90 g / cm 3.
    [15" claim-type="Currently amended] The breathable barrier laminate of claim 14 wherein the laminate has a WVTR greater than 800 g / m 2 / day.
    [16" claim-type="Currently amended] The breathable barrier laminate of claim 9 wherein the laminate has a peel strength of greater than 300 g.
    [17" claim-type="Currently amended] 15. The breathable barrier laminate of claim 14 wherein the laminate has a peel strength of greater than 500 g.
    [18" claim-type="Currently amended] 5. The breathable barrier laminate of claim 4, wherein the base film comprises a linear low density ethylene polymer having a density of greater than 0.90 g / cm 3.
    [19" claim-type="Currently amended] 19. The breathable barrier laminate of claim 18 wherein said fibrous layer comprises a nonwoven web of propylene polymer fibers.
    [20" claim-type="Currently amended] 20. The breathable laminate of claim 19 wherein said nonwoven web comprises spunbond fibers.
    [21" claim-type="Currently amended] The breathable barrier laminate of claim 14, wherein the fibrous layer comprises a nonwoven web of propylene polymer fibers and has a peel strength of greater than about 300 g.
    [22" claim-type="Currently amended] The breathable barrier laminate of claim 9 wherein the peel strength is greater than 500 g with a total basis weight of less than about 35 g / m 2 of the base film and the intermediate film.
    [23" claim-type="Currently amended] The breathable barrier laminate of claim 2 wherein the base film and intermediate film have a total basis weight of less than about 35 g / m 2 and a peel strength of greater than 300 g and a WVTR greater than 800 g / m 2 / day.
    [24" claim-type="Currently amended] The breathable barrier laminate of claim 2 wherein said intermediate film comprises 50% to about 70% filler and said intermediate layer further contains a second ethylene copolymer.
    [25" claim-type="Currently amended] The breathable barrier laminate of claim 24 wherein said second ethylene copolymer is selected from the group of ethylene-vinyl acetate, ethylene-n-methyl acrylate, ethylene butyl acetate, ethylene-propylene and ethylene-alphaolefin copolymers.
    [26" claim-type="Currently amended] The breathable barrier laminate of claim 1 wherein the laminate has a WVTR greater than 800 g / m 2 / day.
    [27" claim-type="Currently amended] 27. The breathable barrier laminate of claim 26 wherein the laminate has a peel strength of greater than 500 g.
    [28" claim-type="Currently amended] 25. The breathable barrier laminate of claim 24 wherein said intermediate film is less than about 15% of the thickness of said base film and said intermediate film and said basis weight of said base film and said intermediate film is less than 35 g / m 2.
    [29" claim-type="Currently amended] 3. The breathable barrier laminate of claim 2 wherein the breathable fibrous layer comprises a nonwoven web and the intermediate film and the nonwoven web are bonded by a plurality of discontinuous adhesion points that make up less than about 30% of the surface area of the laminate. .
    [30" claim-type="Currently amended] 7. The breathable barrier laminate of claim 6 wherein the breathable fibrous layer comprises a nonwoven web, the nonwoven web is point bonded, and the adhesion point comprises less than about 30% of the surface area of the laminate.
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    CN1102500C|2003-03-05|
    DE69838395D1|2007-10-18|
    CA2301814A1|1999-03-25|
    AU9390698A|1999-04-05|
    CA2301814C|2006-11-21|
    AR017055A1|2001-08-22|
    ZA9807679B|1999-02-25|
    BR9811627A|2000-09-19|
    PL339299A1|2000-12-04|
    CN1270555A|2000-10-18|
    RU2192512C2|2002-11-10|
    WO1999014047A1|1999-03-25|
    ID24171A|2000-07-13|
    US6045900A|2000-04-04|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    法律状态:
    1997-09-15|Priority to US08/929,562
    1997-09-15|Priority to US08/929,562
    1998-09-15|Application filed by 로날드 디. 맥크레이, 킴벌리-클라크 월드와이드, 인크.
    1998-09-15|Priority to PCT/US1998/019156
    2001-03-26|Publication of KR20010023957A
    2006-03-28|Application granted
    2006-03-28|Publication of KR100563877B1
    2008-05-13|First worldwide family litigation filed
    优先权:
    申请号 | 申请日 | 专利标题
    US08/929,562|1997-09-15|
    US08/929,562|US6045900A|1997-09-15|1997-09-15|Breathable filled film laminate|
    PCT/US1998/019156|WO1999014047A1|1997-09-15|1998-09-15|Breathable filled film laminate|
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